“What is the most important invention of the twentieth century? Aeroplanes, nuclear energy, space flight, television and computers will be the most common answers. Yet none of these can match the synthesis of ammonia from its elements. The world might be better off without Microsoft and CNN, and neither nuclear reactors nor space shuttles are critical to human well-being. But the world’s population could not have grown from 1.6 billion in 1900 to today’s seven billion without the Haber–Bosch process. Much of the food we eat is grown with some form of synthetic chemical fertilizer derived from the Haber-Bosch process. Due to its dramatic impact on the human ability to grow food, the Haber process served as the ‘detonator of the population explosion.’ ” This is the prognosis of the distinguished Czech-Canadian scientist, policy analyst, professor, and scientist Vaclav Smil. (1)
Smil has published 35 books and more than 400 papers on topics in the fields of energy, food production, nutrition, technical innovation, risk assessment and public policy. He is a Distinguished Professor Emeritus at the University of Manitoba, a Fellow of the Royal Society of Canada (Science Academy), and a Member of the Order of Canada; in 2010 he was listed by Foreign Policy among the top 100 global thinkers.
What is the Haber-Bosch Process?
Fertilizer manufacture is an energy-intensive industry. It has been estimated that fertilizer production accounts for approximately 1.2% of the world’s energy use, of which about 93% is consumed by nitrogen-based fertilizers.(2) The two raw materials for the reaction are obtained-nitrogen and hydrogen. The major source of hydrogen is methane from natural gas. Impurities are removed from the gasses through a process called scrubbing. Once scrubbed, both gasses are mixed, and the mixture is piped into a compressor. Gases are passed over four beds of catalyst, with cooling between each pass so as to maintain a reasonable equilibrium constant. On each pass only about 15% conversion occurs, any unreacted gases are recycled, and eventually an overall conversion of 97% is achieved. Ammonia is collected in tanks as a liquid, and stored under pressure. (3)
Why has the Haber-Bosch process been so important?
Of all the innovations of the 20th century, none has made more of a difference to our survival than the Haber–Bosch process. Nearly 80% of the nitrogen found in human tissues originated from this method.(4) The importance of being able to produce ammonia is significant, because ammonia is the building block for nitrogen-containing compounds. Ammonia is used in the production of essentially all nitrogen compounds, and nitrogen in turn is necessary for the manufacture of artificial fertilizers, which provide nutritional support for plant growth. The ability to fix nitrogen used to produce fertilizers allows plant yields to increase, providing food for rapidly growing populations. Hence, food production expanded dramatically during the 20th century.
Addicted to the Haber Bosch Process
The Haber process now produces 450 million tonnes of nitrogen fertilizer per year, mostly in the form of anhydrous ammonia, ammonia nitrate, and urea. This equates to the consumption of between 3–5% of the world’s natural gas production for this process alone. (5) To understand just how widespread, and how much, artificial fertilizers are used worldwide, we can look at the per kilogram per hectare data from the world bank. Australia uses 44.7 kg per hectare, Brazil 181, Canada 74.4, Chile 358, China 647, Germany 199, Ireland 387, Jordan 1,260, Malaysia 1,570, New Zealand 1,485, Qatar 12,087, UK 234, and the U.S 131 kg per hectare.(6) Typically mass produced crops such as wheat, cotton, corn, soybean, rice, sorghum, coffee, cocoa, citrus, sugar cane, potatoes, sunflowers, fruits and vegetables are the main users of various combinations of artificial fertilizers.
It is not only crops which add to increased use of nitrogen based fertilizers. In dairy and cattle farming nitrogen is used to improve pasture growth. This adds to a vicious circle of excess nitrogen in natural ecosystems. Artificial nitrogen and phosphorous are added to improve crops for intensive farming, cattle release further nitrogen (contained in urine) as urea which enters waterways. Too much nitrogen (in the form of ammonia or nitrate) is highly toxic to fish and some other aquatic organisms. Both raw sewage and dairy shed effluent are rich in ammonia. The much more common and widespread impact of nutrient pollution – excessive growth of unwanted plants – occurs at lower nitrogen levels. Excessive growth of unwanted plants, such as slime, algae, and choking weeds, degrades swimming and fishing spots and depletes oxygen in the water, sometimes to the point of suffocating aquatic life. (7)
The Problem With Artificial Fertilizers?
Like an athlete receiving a shot of steroids to improve performance, artificial fertilizers help plant growth in the short-term. Over the long-term it creates a deadly cycle. It takes hundreds of years to build just inches of quality topsoil. Yet with industrial mono-cropping agriculture combined with artificial fertilizers to give plants a spike, nothing is done to build soils for the future. Most of the areas that use extensive artificial fertilizers would not produce a crop without massive amounts of fertilizers continually added to the soil to support plant growth. Synthetic fertilizers create serious imbalances in the nitrogen cycle and negatively impact soil organisms, and runoff from excessive nitrogen creates dead zones in rivers and oceans.
To a certain extent there are diminishing returns for this synthetic method of farming. In parts of India where the “Green Revolution” took hold (a combination of high-yielding varieties of cereal grains, expansion of irrigation infrastructure, modernization of management techniques, distribution of hybridized seeds, and the widespread use of synthetic fertilizers and pesticides), great results were produced in the short term but parts of India were also decimated and now lie as barren wastelands. As commodities such as oil and gas become harder to acquire and potentially more expensive, the production and cost structure of synthetic fertilizers will be impacted.
So What to Do?
- Learn how to build your own soil through composting
- Start a worm farm
- Grow your own food
- Learn about Permaculture
- Plant a food forest
- Learn about crop rotation
- Reduce your reliance on the supermarkets
- Support farmers markets and small organic growers who use compost and build soils
- Learn about nitrogen fixing plants such as legumes, cow pea, vetch , clover, lupins, etc.
- Reduce or eliminate consumption of “industrial scale farming” products
Article by Andrew Martin, author of Rethink…Your world, Your future. and One ~ A Survival Guide for the Future…
Source: excerpts from Rethink…Your world, Your future.
(1) http://vaclavsmil.com/wp-content/uploads/docs/smil-article-1999-nature7.pdf
(2) http://large.stanford.edu/courses/2014/ph240/yuan2/
(3) https://thehaberboschprocess.wordpress.com/the-process/the-process-2/
(4) Howarth, R. W. (2008). “Coastal nitrogen pollution: a review of sources and trends globally and regionally”. Harmful Algae 8: 14–20. doi:10.1016/j.hal.2008.08.015.
(5) Smil, Vaclav (2004). Enriching the Earth: Fritz Haber, Carl Bosch, and the Transformation of World Food Production. Cambridge, MA: MIT Press. ISBN 9780262693134.
(6) http://data.worldbank.org/indicator/AG.CON.FERT.ZS
(7) http://www.pce.parliament.nz/assets/Uploads/PCE-Water-quality-land-use-web-amended.pdf